Copper is the good choice over PEX for outside plumbing..As, Copper has natural quality that make it ideal for plumbing. It creates a bio-static atmosphere which makes it difficult for bacteria to grow inside of it. It also resists corrosion and is unaffected by ultraviolet rays, which allows you to use it outdoors.
While PEX is not suitable for use outside, it is much more resistant to freezing temperatures and bursting.